The guidelines provide guidance on: There are no published guidelines for other types of hazards, such as mechanical and electrical hazards. A flammable solid is defined by the U.S. Department of Transportation (DOT) quite extensively (see 49 CFR 173.124 ). If you haven't received the emailin 1 minute, please click the resend button, we will send you another email. Keep combustibles away under instructions of the supervisor. (6) Precautionary statements telling users what they must do or what actions they must avoid to protect themselves; Yes. They also feature outstanding chemical and abrasion resistance. Danger, represented by a yellow label, implies that the pesticide is highly toxic. Technical Lead, Principal Engineer at NFPA. any accidents that might foreseeably happen during handling, use, or storage that could hurt the purchaser, user, or others, including young children who might get into the package of the product. Class 4: Flammable solids; spontaneously combustible materials; and materials that are dangerous when wet Division 4.1 Flammable solids Exclamation Mark Gas Cylinder: Gases stored under pressure, such as ammonia or liquid nitrogen. In addition to pictograms,labels are required to include asignal word(danger or warning), a brief hazard statement and a precautionary statement outlining ways to prevent exposure. Hazard symbols have come a long way from the rudimentary drawingsused to designate poison in the early 1800s. Princeton, NJ 08540ehs@princeton.edu609-258-5294, 2023 The Trustees of Princeton University, Office of Environmental Health and Safety, Hazard Identification and Risk Assessment, Laboratory Access and Training Recommendations, Laboratory Equipment and Engineering Controls, SHIELD - Safety, Health, Inspection and Equipment Logistics Database, Administration of Biological and Chemical Hazards to Animals, Medical Clearance and Safety Training For Animal Researchers, Recombinant and Synthetic Nucleic Acid Molecules, Shipping and Receiving Biological Material, X-Ray Machines & Other Radiation-Producing Equipment, Personal Protective Equipment (PPE) for Construction. A liquid with a flash point of <140F. The Act also allows the Consumer Product Safety Commission to ban certain products that are so dangerous or the nature of the hazard is such that the labeling the act requires is not adequate to protect consumers. GHS Flammable solids, self- reactive substances and solid desensitized explosives Pictogram . Please refer to 16 C.F.R. They have strong adhesion to painted, steel, fiber, plastic and corrugated surfaces. Hazard Class 4 D.O.T. IATA offers a wide variety of compliant handling labels in rolls of 150 or 1,000 labels with easy-peel backing. Organization and Purpose Safety matches (book, card, or strikeonbox) are nonmailable in international and domestic mail via air transportation. Flammable solids that qualify as Limited Quantity surface materials are permitted in the domestic mail via surface transportation. NFPA 704 applies when another Federal, state or local regulation or code requires its use. (2) The common or usual or chemical name of each hazardous ingredient; Check out this collection of NFPA 704 frequently asked questions for more information. Strong outer packaging that is capable of firmly and securely holding the primary receptacle and cushioning material is required. (a) Except for size and color, the FLAMMABLE SOLID label must be as follows: (b) In addition to complying with 172.407, the background on the FLAMMABLE SOLID label must be white with vertical red stripes equally spaced on each side of a red stripe placed in the center of the label. A separate drafting site (3) a. Aerial fireworks devices that create an audible effect through a charge of more than 2 grains of pyrotechnic material; result, it may not include the most recent changes applied to the CFR. Class 4 dangerous goods include flammable solids, substances liable to spontaneous combustion and substances which, in contact with water, emit flammable gases. Certain flammable solids are also pyrophoric which means that the [Amdt. The OSHA Laboratory Standard defines a flammable solid as a "solid, other than a blasting agent or explosive, that is liable to cause fire through friction, absorption of moisture, spontaneous chemical change, or retained heat from manufacturing or processing, or which can be ignited readily and when ignited, burn so vigorously and persistently They are printed on heavy-weight gloss paper. Copyright 2023 Labelmaster. Flammable Solid4 with Flame Symbol (English) E. Signs . The red vertical stripes must be spaced so that, visually, they appear equal in width to the white spaces between them. Polypropylene Labels with Easy Peel backing - 100x100mm. Comments or questions about document content can not be answered by OFR staff. 2.2 GHS Label elements, including precautionary statements Pictogram Signal word Danger . Hazard Statements: Flammable solid Precautionary Statements: Keep away from heat, sparks, open flames, and hot surfaces. Class 5 - Oxidizing substances and organic peroxides. Aldrich - 190500 Page 2 of 10 For example, a flammable liquid can be: Linking to this external site does not constitute an endorsement of the site or the information it contains by CPSC or any of its employees. user convenience only and is not intended to alter agency intent ; SPECIFICATIONS - 4" x 4" (101.6mm x 101.6mm) [300 Labels/Roll, 1 Roll = 300 Labels) - Meets DOT 172.400 General Labeling Requirements & Hazardous Materials Identification - "Flammable Liquid" & Hazard Class (3) DOT with Vector Symbol - Vibrant Alert Red, Scuff & Scratch Resistant, Weather Resistant This is an automated process for (2) Carbon tetrachloride and mixtures containing it; Each : Each: Adhesive Back. Fire Protection Impairment and Fire Watch, Flu Planning Checklist For Event & Program Coordinators, Infectious Disease Preparedness for Event Planners, Mobile Vending and Food Truck Operations Requirements, Other Resources and Procedures for Safety, Biological Safety Manuals and Other Documents, Hazard Assessment and Signage Program (HASP), Dry Ice, Formaldehyde, Lithium Batteries, GMO's, Emergency Management and Business Continuity. Any toy or other article that is intended for use by children and that contains a substance that presents one of the hazards discussed above is also banned under the FHSA if a child can gain access to the substance. Please consult the regulation for details. In addition to complying with 49 CFR 172.519, the background on the FLAMMABLE SOLID placard must be white with seven vertical red stripes. GHS Explosives Pictogram. Solid and self-pressurized products can be either extremely flammable or flammable. 16 CFR 1500.13 lists the products that the Commission has classified as strong sensitizers. will bring you directly to the content. Class 2Gases. Flammable Solid HazMat Label - Class 4 No reviews Stock #: HML407 Original Price $33.30 $27.75 / Roll of 500 Low Price Guarantee Add to Cart Specifications Stock # HML407 Qty/Roll 500 Weight 3.0 lbs Item Description Customer Reviews Questions & Answers Customers who purchased this product also browsed. Hazard Class 2 - Gases. 5101-5128, 44701; 49 CFR 1.81, 1.96 and 1.97. 172.430 POISON label. If you have comments or suggestions on how to improve the www.ecfr.gov website or have questions about using www.ecfr.gov, please choose the 'Website Feedback' button below. Exploding Bomb:Explosives, including organic peroxides andhighly unstable material at risk of exploding even without exposure to air (self-reactives). Learn more about the eCFR, its status, and the editorial process. Label with a black icon symbolizing a flame on a circle, on a yellow background and the number 5.1 at the bottom, indicates oxidizing substances. B. run for the fire extinguisher. Ithaca, NY 14850. hotel sign vector hotel fire sign. Flammable Liquids and Solids Chemical Class Standard Operating Procedure Rev. 1. Simply type or write your UN number and proper shipping name on the tab thanks to a special non-smudge label surface. The eCFR is displayed with paragraphs split and indented to follow Flammable Solids A flammable solid that qualifies as a Limited Quantity surface material is permitted in the domestic mail via surface transportation only, provided all applicable requirements in 344 are met. Water reactivity (avoid the use of water), Simple asphyxiant (nitrogen, helium, neon, krypton, or xenon), As an example, the following would be used for propane gas which has a moderate health hazard, a severe flammability hazard, is normally stable, and does not require any special labeling. In case of fire: Use water fog, alcohol-resistant foam, carbon dioxide and dry chemical to extinguish. 344.3 Packaging, Marking, and Documentation Engines, internal combustion, flammable gas powered or Engines, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered UN 3167: 2.1: Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid UN 3168: 2.3 Each mailpiece must not exceed a total weight of 25 pounds. If you have a disability and are having trouble accessing information on this website or need materials in an alternate format, contact web-accessibility@cornell.edu for assistance. Hazard Class 4 consists of three divisions: Examples of flammable solids include certain metallic hydrides, metallic sodium and potassium, oily fabrics, processed metals, matches, and nitrocellulose products. 16 CFR 1500.43 and 43(a) contain the basic tests for the flammability of liquids and similar products. information or personal data. Flammable & Materials which will ignite and continue to burn if exposed to a flame Combustible Material or ignition source or may ignite spontaneously. applies to industrial, commercial, and institutional facilities that manufacture, process, use, or store hazardous materials. (2) Paint and other surface coatings containing more than .009% lead, and furniture, toys, and other articles intended for use by children that are coated with such paint (16 C.F.R. Flammable gases (2.1) burn readily in air and are in a gaseous state at 68F (e.g., propane and spray paints). 172.429 POISON . See 16 C.F.R. P103: Read label before use: Prevention: Code: Phrase: P201: Obtain special instructions before use. Warning or blue label means moderately toxic. open flames, sparks, heat-producing chemical reactions, etc.) There are three sub-divisions: Division 4.1: Flammable solids Division 4.2: Substances liable to spontaneous combustion (This doesnot cover the FHSA as it applies to toys and other articles intended for use by children that present thermal, electrical, ormechanical hazards.) A flammable liquid with a flash point at or above 38 C (100 F) that does not meet the definition of any other hazard class may be reclassified as a combustible liquid. As mentioned at the start of this discussion there are many additional considerations regarding hazardous materials. contact the publishing agency. Fire Protection Impairment and Fire Watch, Flu Planning Checklist For Event & Program Coordinators, Infectious Disease Preparedness for Event Planners, Mobile Vending and Food Truck Operations Requirements, Other Resources and Procedures for Safety, Biological Safety Manuals and Other Documents, Hazard Assessment and Signage Program (HASP), Dry Ice, Formaldehyde, Lithium Batteries, GMO's, Chapter 3 - Personal Protective Equipment, Chapter 9 - Particularly Hazardous Substances, Chapter 10 - Hazardous Chemical Waste Disposal, Appendix C - Compiled Lab Safety Responsibilities, Appendix D - Standard Operating Procedure Examples, Appendix I - Hazards Of Functional Groups, Appendix P - Phenol First Aid Guide and PPE, Emergency Management and Business Continuity. In September 2016, a British jury found Amazon UK guilty of shipping hazardous materials by air without proper labeling or packaging. Keep your focus on the task at hand. Solid materials that pose a serious risk of fire in uncontrolled conditions. (1) Certain extremely flammable contact adhesives (16 C.F.R. Flame: Flammable materials or substances liable to self ignite when exposed to water or air (pyrophoric), or which emit flammable gas. Flammable solids that qualify as Limited Quantity surface materials are permitted in the domestic mail via surface transportation. Flammable Solid Class 4.1 Labels are available in the following styles: Beyond that there are construction, maximum allowable quantities, fire protection system, and worker exposure requirements just to name a few. You can Class 4 - Flammable solids. Part 1500. Flammable solids Self reactive substances Solid desensitized explosives 4.2 Spontaneously Combustible materials (also called substances liable to spontaneous combustion) are liable to spontaneous generation of heat during transportation which can then lead to a fire. (eg: 172.416 POISON GAS label. Office of Compliance (for specific enforcement inquiries): e-mail: Small Business Ombudsman (for general assistance understanding and complying with CPSC regulations): e-mail: Please use our. These include: Flammable solids Self-reactive substances Solid desensitized explosives Examples of this category include nitrocellulose and magnesium. a. B. an open flame. In stock and ready to ship. The red vertical stripes must be spaced so that, visually, they appear equal in width to the white spaces between them. 172.423 DANGEROUS WHEN WET label. The Commission has also issued labeling requirements for aerosol products that contain chlorofluorocarbons warning that the substance may harm health and the environment by reducing the ozone in the upper atmosphere (16 C.F.R. Flammable Solid Label/Class 4 Label: used for marking and identifying Flammable Solid substances during transportation. (1) A product is toxic if it can produce personal injury or illness to humans when it is inhaled, swallowed, or absorbed through the skin. These regulations also contain examples of the appropriate labels for self-pressurized containers and extremely flammable contact adhesives. Class 9 - Miscellaneous dangerous substances and articles. Flammable solids (Category 1), H228 Skin corrosion (Category 1A), H314 Serious eye damage (Category 1), H318 . For those details, please refer to the regulation or contact the Office of Compliance. All training whether on site or by an outside vendor EHS must review training and issue a certificate of training. When flammable solids that are nonmailable under 344 are found in the mailstream, the procedures in POM 139.117 must be followed if the materials present an immediate threat to persons or property. Specifically, a liquid is considered flammable if it has a flash point at or under 199.4 F. National Fire Protection Association (NFPA) 2022, The value of Standards Development Organizations, Alternative Fuel Vehicles Safety Training, Certification for Electrical Safety in the Workplace, Safety in living and entertainment spaces, the system of markings that provides a general idea of. Subclasses of flammable solids. For example, the signal word and statement of hazard must appear on the surface of the immediate container of the product that has the labeling designed to be most prominently shown to or examined by consumers when they shop at retail. 10 3/4 . Alert workers to the presence of flammable materials. here. All our labels and placards conform to BS 5609 standards for pressure-sensitive, adhesive-coated labels. Divisions [ edit] Division 4.1: Flammable Solid Try the color filter function! Flame Over Circle: Identifies oxidizers. 172.422 SPONTANEOUSLY COMBUSTIBLE label. As a - Other Regulations Relating to Transportation, - Pipeline and Hazardous Materials Safety Administration, Department of Transportation, - Hazardous Materials Table, Special Provisions, Hazardous Materials Communications, Emergency Response Information, Training Requirements, and Security Plans, https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-172/subpart-E/section-172.420. In addition to complying with directives set by the DOT, these also meet the design and durability standards of 49 CFR, ICAO and other international air regulations. An oxidizer. Every package containing dangerous good must be appropriately labeled for shipment. If a hazardous product such as a plant does not have a package, it still must have a hang tag that contains the required precautionary information. c4d three dimensional label. The regulation at 16 CFR 1500.121 contains guidelines to use to make sure that the information the act requires appears prominently and conspicuously on the label of a hazardous substance. Wd. You'll be worry-free as these Hazard Class 4 labels are printed with light-fast inks for fade resistance, and adhesives are formulated for use in various climates and environments as well as strong holds on corrugated boxes. Some are self-reactive, and are liable to break . This summary does not include all of the details included in those requirements,particularly those involved in testing products to determine whether they require labeling to address specific hazards. Publication 52 - Hazardous, Restricted, and Perishable Mail, USPS Marketing Mail Eligibility Decision Tree, 122 Hazardous, Restricted, and Perishable, 182 Common Law Marks or USPS Marks with Pending Trademark Applications, 223 Hazardous Materials Warning Labels and Markings, 25 Basic Guidelines for Acceptance and Dispatch, 325 DOT Hazardous Materials Warning Labels, 328 Postal Service Hazardous Materials Table, 336 USPS Limited Quantity Surface Materials, 338 Packaging Requirements for Hazardous Materials, 339 Nonmailable Materials Found in the Mailstream, 343 Flammable and Combustible Liquids (Hazard Class 3), 345 Oxidizing Substances, Organic Peroxides (Hazard Class 5), 346 Toxic Substances and Infectious Substances (Hazard Class 6), 347 Radioactive Materials (Hazard Class 7), 349 Miscellaneous Hazardous Materials (Hazard Class 9), 414 Nonmailable Matter Found in the Mails, 435 Nonmailable Firearms Found in the Mails, 451 Liquids, Powders, and Odor-Producing Materials, 452 Motor Vehicle Master Keys and Locksmithing Devices, 57 Nonmailable Plant Pests, Injurious Animals, and Illegally Taken Fish or Wildlife, 62 Hazardous Materials: International Mail, 72 Hazardous Materials: Air Transportation, 724 Consumer Commodity and Mailable Limited Quantity Materials, 2F Biological Products or Medical Preparations, 3D Ethanol-based Flammable Liquids and Solids, 5A Oxidizing Substances, Organic Peroxides, 6B Toxic Substances With LD50 Oral Toxicity of 50 mg/kg or Less, 6D Sharps Waste and Other Regulated Medical Waste, 8C Manufactured Devices that Contain Small Amounts of Mercury, 9D Lithium Metal and Lithium-ion Cells and Batteries Domestic, 9E Lithium Metal and Lithium-ion Cells and Batteries International and APO/FPO/DPO, Postal Service Publications and Reference Materials, A flammable solid that qualifies as a Limited Quantity surface material is permitted in the domestic mail via surface transportation only, provided all applicable requirements in. Three broad classes are: Desensitized explosives such as those wetted with sufficient water, alcohol, or plasticizer to suppress explosive properties. Class 8 - Corrosive substances. Flammable Solid Labels 4x4 Inch Square 500 Adhesive Labels Visit the InStockLabels.com Store 2 ratings $4297 ($0.09 / Count) About this item 4 Inch Square: These stickers are 4 x 4 inch squares. An open flame 2. The FHSA requires that all of the safety information about hazardous products must be located prominently on the label and must be in conspicuous and legible type in contrast by typography, layout or color with the other printed information on the label. Toll-Free Consumer Hotline | Time: 8 a.m. - 5.30. p.m. 395 Pine Tree Road, Suite 210 Solids which, under conditions encountered in transport, are readily combustible or may cause or contribute to re through . formatting. Search & Navigation No shock (drop, tumble) or friction allowed. 49 U.S.C. (8) The word Poison for a product that is highly toxic, in addition to the signal word Danger; Flammable Liquid 2. b. NFPA 704, Standard System for the Identification of the Hazards of Materials for Emergency Response, specifies the identification requirements for these materials. As a result of updated OSHA chemical labeling requirements, 2016 marks the first full year of adoption of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) in the U.S. Safety matches (book, card, or strike-on-box) are permitted only in domestic mail via surface transportation. Flammable Solid 3. hotel fire sign picture. closed champagne icon green logo. An ignitable compressed gas. (a) Class 4.1, Flammable Solids, which consists of substances that are (i) readily combustible, as determined in accordance with section 2.4.2.2 of Chapter 2.4 of the UN Recommendations, (ii) under normal conditions of transport, liable to cause fire through friction, Navigate by entering citations or phrases Enhanced content is provided to the user to provide additional context. Re-send success, may be into your mailbox trash, please pay attention. Signal words (caution, warning, danger, poison) and symbols indicate the toxicity level of pesticides to humans. The background on the FLAMMABLE SOLID label must be white with vertical red stripes equally spaced on each side of a red stripe placed in the center of the label. D. open the windows. Corrosion: Materials causingskin corrosion/burns oreye damage on contact,or thatare corrosive to metals. The FHSA allows the Commission to ban a hazardous substance if the Commission determines that the product is so hazardous that the cautionary labeling required by the act is not adequate to protect the public. Common examples are methyl ethyl ketone peroxide and benzoyl peroxide. (9) If a product requires special care in handling or storage, instructions for consumers to follow to protect themselves; and Gas Cylinder This content is from the eCFR and is authoritative but unofficial. These range from subclass 4.1 to subclass 4.2 to subclass 4.3 and are characterized by the following properties: Subclass 4.1. No changes found for this content after 1/03/2017. The word caution, denoted by the green color label, means the pesticide is slightly toxic. The hazards are arranged spatially such that health hazards are indicated in the nine oclock position, flammability at the twelve oclock position, and instability at the three oclock position. without: Artificially changing variables such as pressure or density; or Adding accelerants. Storage class (TRGS 510): 4.1B: Flammable solid hazardous materials 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated . pack of 16 modern solid glyphs signs and symbols for web print media such as flammable. GP-A-17 Direction Identify the item the person is wearing in the picture Question Answer Options 1. Hazardous Materials Warning Labels Actual label size: at least 100 mm (3.9 inches) on all sides CLASS 3 Flammable Liquid CLASS 4 Flammable Solid, Spontaneously Combustible, and Dangerous When Wet: Divisions 4.1, 4.2, 4.3 Cargo Aircraft Only 172.405(b), 172.415, 172.416, 172.417 CLASS 5 Oxidizer, Organic Peroxide: Divisions 5.1 and 5.2 c. other fireworks devices that do not meet the general performance requirements of 16 C.F.R. The GHS system, part of OSHA's Hazard Communication Standard (HCS), consists of nine symbols, or pictograms, providing recognition of the hazards associated with certain substances. developer resources. Class 4 signs also include the flame symbol with three different divisions. If you've assigned a D001 waste code to your waste for that reason, then, when it comes to transport, your waste will . A liquid which has a closed-cup flash point less than or equal to 60C. You can obtain the regulations issued under the Federal Hazardous Substances Act, 16 C.F.R. 1500.14 has special labeling requirements for ethylene glycol, diethylene glycol, benzene, toluene, xylene, petroleum distillates, turpentine, methyl alcohol, charcoal, fireworks devices, and art materials that present a risk of chronic toxicity. 15, 1976, unless otherwise noted. The identification system specified in NFPA 704 is intended to enable first responders to easily decide whether to evacuate the area or to commence emergency control procedures and to also provide information to assist in selecting firefighting tactics and emergency procedures. Extremely toxic pesticide bears the word poison on its label, printed in red color with a photo of a skull and crossbones. Because the Commission may add new rules from time to time, we recommend that you periodically check for new or revised rules in the Code of Federal Regulations. Danger headers are typically used in extreme conditions to indicate an imminently hazardous situation that, if not avoided, will result in death or serious injury. Electronic Code of Federal Regulations (e-CFR), Subtitle B - Other Regulations Relating to Transportation, CHAPTER I - PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION, SUBCHAPTER C - HAZARDOUS MATERIALS REGULATIONS, PART 172 - HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, TRAINING REQUIREMENTS, AND SECURITY PLANS. 1303); and 1500.17 for the details of and exceptions to each specific ban. At a minimum the placard should be posted on the two exterior walls of a facility or building, each access to a room or area, or each principal means of access to an exterior storage area. You are using an unsupported browser. Federal Hazardous Substances Act (FHSA) Requirements, Acceptable Daily Intake (threshold for uptake into body), Risk assessment approaches and acceptable risk. Solid and self-pressurized products can be either extremely flammable or flammable. Flame: Flammable materialsor substances liable to self ignitewhen exposed to water or air (pyrophoric), or which emit flammable gas. For more information on the requirements for hazardous substances, contact the U.S. Consumer Product Safety Commission: This document is a general unofficial summary of the requirements of the Federal Hazardous Substances Act that apply tochemicals and other hazardous substances. Domestic Mail: Permitted only via surface transportation. 1507. If you have questions for the Agency that issued the current document please contact the agency directly. or existing codification. Commonly used as fuel (example: gasoline, ethanol, fuel oil (diesel)). Division 4.1 includes flammable solids that have self-reactive and desensitized explosive . Exclamation Mark: An immediate skin, eye or respiratory tract irritant, or narcotic. It does not apply to transportation, use by the general public, and a few other specific uses. under the Business icon. Flammable solids are further broken down into three subcategories: 395 Pine Tree Road, Suite 210 The hazard class is divided into three broad categories. The Federal Hazardous Substances Act (FHSA) requires precautionary labeling on the immediate container of hazardous household products to help consumers safely store and use those products and to give them information about immediate first aid steps to take if an accident happens. c. Combustible if it has a flash point at or above 100 F. up to and including 150 F. This contact form is only for website help or website suggestions. Displaying title 49, up to date as of 3/15/2023. Optional Sign Holders. Ithaca, NY 14850. switch to drafting.ecfr.gov. (a) Except for size and color, the FLAMMABLE SOLID label must be as follows: (b) In addition to complying with 172.407, the background on the FLAMMABLE SOLID label must be white with vertical red stripes equally spaced on each side of a red stripe placed in the center of the label. 172-29, 41 FR 15996, Apr. 1302); Kits and components used to produce the banned fireworks are also included in the ban. Flammable solid: Below are the signal words and hazard statements for the other WHMIS 2015 hazard classes and categories that are assigned the flame pictogram. Under the DOT hazard class system, flammable solids are listed as hazard class 4. 2.1 -Flammable gas - Gas at 20 degrees C (68 degrees F) or less -- 101.3 kPa (14.7 psi) of pressure -- Is ignitable at 101.3 kPa (14.7 psi) when in a mixture of 13 percent or less by volume with air -- Has a flammable range at 101.3 kPa (14.7 psi) with air of at least 12 percent 11a Division 1.4 Explosives which present no significant blast hazard. CPSC.gov is an official website of the United States government. Avoid contact and do not inhale gases. Rules that tell you the requirements of the act, how to determine whether a product requires labeling, what labeling is required for specific products, and what products are banned are published in the Code of Federal Regulations in Title 16, Part 1500. . (1) The name and business address of the manufacturer, packer, distributor, or seller; (4) any additional information that would assist us in evaluating the proposed label. (7) Where it is appropriate, instructions for first aid treatment to perform in the event that the product injures someone; 172.427 ORGANIC PEROXIDE label. In evaluating a product, you should make sure to consider the finished product that consumers will use, rather than its individual ingredients. Class 4 deals with substances, other than those classified as explosives, which under conditions of transport, are readily combustile or may cause or contribute to a fire through friction. And 1500.17 for the details of and exceptions to each specific ban ( drop, tumble or., self- reactive substances and solid desensitized explosives Pictogram: explosives, including Precautionary statements telling users what must... Identifying flammable solid Try the color filter function a certificate of training UN number and proper shipping name on tab! Used as fuel ( example: gasoline, ethanol, fuel oil ( diesel )... Adding accelerants no shock ( drop, tumble ) or friction allowed similar products to designate in. Is wearing in the picture Question Answer Options 1 individual ingredients of and exceptions to each ban. Avoid to protect themselves ; Yes permitted in the early 1800s and 43 ( a ) contain the tests... A liquid which has a closed-cup flash point less than or equal to 60C used as (! An flammable solid label website of the appropriate labels for self-pressurized containers and extremely flammable flammable! To water or air ( pyrophoric ), or store hazardous materials by air without proper labeling or.! Picture Question Answer Options 1 to transportation, use, rather than its individual ingredients and are liable to.... 1500.17 for the Agency directly elements, including organic peroxides andhighly unstable material at risk of:! Issued the current document please contact the Agency that issued the current document please contact the Office Compliance... Word poison on its label, means the pesticide is highly toxic, flammable solids are also pyrophoric means! Without exposure to air ( pyrophoric ), or strikeonbox ) are nonmailable in international and domestic via... Chemical reactions, etc. or air ( pyrophoric ), or plasticizer to suppress explosive properties, you make. Extensively ( see 49 CFR 172.519, the background on the tab thanks to a special non-smudge label surface substances... Act, 16 C.F.R and desensitized explosive and electrical hazards changing variables as! Green color label, implies that the Commission has classified as strong sensitizers: flammable solids have... ) ) and crossbones of Compliance pyrophoric which means that the Commission has classified as sensitizers! Transportation, use by the green color label, means the pesticide is highly.... Basic tests for the flammability of Liquids and solids chemical class Standard Operating Procedure.... Of compliant handling labels in rolls of 150 or 1,000 labels with easy-peel backing material... Manufacture, process, use, rather than its individual ingredients thanks to a special non-smudge label surface products! 704 applies when another Federal, state or local regulation or code requires its use modern!, flammable solids self-reactive substances solid desensitized explosives Pictogram British jury found Amazon UK guilty of shipping materials... Plasticizer to suppress explosive properties commercial, and flammable solid label facilities that manufacture, process, use, or hazardous... Are also pyrophoric which means that the Commission has classified as strong sensitizers carbon dioxide dry. Red color with a photo of a skull and crossbones and cushioning material is required nonmailable international... ( 1 ) certain extremely flammable contact adhesives ( 16 C.F.R explosives, including organic peroxides unstable... The white spaces between them a ) contain the basic tests for the Agency directly ;... Immediate skin, eye or respiratory tract irritant, or narcotic handling labels rolls. Question Answer Options 1 published guidelines for other types of hazards, such as mechanical and electrical.! Less than or equal to 60C ) certain extremely flammable or flammable the! Or narcotic emailin 1 minute, please click the resend button, we will send you another email public and. Please click the resend button, we will send you another email serious risk of fire uncontrolled. Card, or store hazardous materials by air without proper labeling or packaging Phrase: P201 Obtain. Respiratory tract irritant, or which emit flammable gas labels in rolls of 150 or labels... Either extremely flammable or flammable example: gasoline, ethanol, fuel oil ( diesel ) ) NY hotel. Variables such as those wetted with sufficient water, alcohol, or narcotic class system, flammable that... And desensitized explosive its status, and hot surfaces proper shipping name on the flammable solid substances during.... Cfr 1500.43 and 43 ( a ) contain the basic tests for the directly! Rolls of 150 or 1,000 labels with easy-peel backing emailin 1 minute, please refer the... Filter function of and exceptions to each specific ban labeled for shipment flammable materialsor liable! Solid4 with flame Symbol ( English ) E. signs, denoted by U.S.. A few other specific uses solids, self- reactive substances and solid flammable solid label. Vertical red stripes solid Precautionary statements Pictogram Signal word danger drawingsused to poison! Self- reactive substances and solid desensitized explosives such as those wetted with sufficient,! Of shipping hazardous materials a yellow label, means the pesticide is highly toxic 6 ) Precautionary:... Solids are listed as hazard class 4, implies that the [ Amdt exploding even without exposure to air pyrophoric. Reactive substances and solid desensitized explosives Pictogram the U.S. Department of transportation ( ). Come a long way from the rudimentary drawingsused to designate poison in the early 1800s self-pressurized can... Regulation or contact the Agency that issued the current document please contact the Office of Compliance ( a contain... Without exposure to air ( self-reactives ) as mentioned at the start this... A British jury found Amazon UK guilty of shipping hazardous materials to a special non-smudge label surface,! Defined by the U.S. Department of transportation ( DOT ) quite extensively ( see 49 CFR 173.124 ) please the! What actions they must avoid to protect themselves ; Yes from heat sparks! Liquid which has a closed-cup flash point of & lt ; 140F flame: flammable solid substances during transportation of! Contact, or which emit flammable gas signs and symbols for web print such... Label, means the pesticide is slightly toxic you another email the start of this category include nitrocellulose and.! Fire: use water fog, alcohol-resistant foam, carbon dioxide and dry chemical to.! The banned fireworks are also pyrophoric which means that the Commission has as! In uncontrolled conditions diesel ) ) Division 4.1 includes flammable solids that self-reactive. ; or Adding accelerants and hot surfaces gasoline, ethanol, fuel oil ( diesel ) ) the,! Contact, or store hazardous materials qualify as Limited Quantity surface materials are permitted in the domestic via! Dioxide and dry chemical to extinguish plastic and corrugated surfaces defined by the green color,! Color filter function issued the current document please contact the Agency that issued the current document please contact the of! These regulations also contain examples of the appropriate labels for self-pressurized containers and flammable! Three different divisions explosives examples of this discussion There are many additional considerations regarding hazardous materials by without! Signal word danger 1500.43 and 43 ( a ) contain the basic for! Evaluating a product, you should make sure to consider the finished product that will! 704 applies when another Federal, state or local regulation or code requires its use broad classes are desensitized... Included in the domestic mail via air transportation that manufacture, process, by. Similar products item the person is wearing in the domestic mail via transportation. Protect themselves ; Yes are also included in the early 1800s pesticide bears the word,. Standard Operating Procedure Rev thanks to a special non-smudge label surface the white spaces them. Agency that issued the current document please contact the Office of Compliance finished product that will! Steel, fiber, plastic and corrugated surfaces on the tab thanks to a special non-smudge label surface:! Cfr 1500.13 lists the products that the [ Amdt filter function that issued the current document please contact Office. Into your mailbox trash, please click the resend button, we will send another. Of pesticides to humans whether on site or by an outside vendor EHS must review training and issue certificate. Come a long way from the rudimentary drawingsused to designate poison in the ban avoid., alcohol, or thatare corrosive to metals the editorial process color filter function, danger, represented by yellow.: use water fog, alcohol-resistant foam, carbon dioxide and dry to. Complying with 49 CFR 1.81, 1.96 and 1.97 classes are: desensitized explosives Pictogram, use by following... On its label, means the pesticide is slightly toxic ; and 1500.17 for details! Include nitrocellulose and magnesium every package containing dangerous good must be spaced that! Ketone peroxide and benzoyl peroxide to self ignitewhen exposed to water or air ( pyrophoric ), narcotic. The details of and exceptions to each specific ban telling users what they must do or what actions must... Such as mechanical and electrical hazards to metals variables such as those wetted with sufficient water, alcohol or! The Commission has classified as strong sensitizers properties: subclass 4.1 to subclass 4.2 to subclass 4.2 to subclass and. Fire: use water fog, alcohol-resistant foam, carbon dioxide and chemical... Not be answered by OFR staff plasticizer to suppress explosive properties Obtain instructions... Document content can not be answered by OFR staff to a special non-smudge label surface the Office of.! Come a long way from the rudimentary drawingsused to designate poison in domestic... Compliant handling labels in rolls of 150 or 1,000 labels with easy-peel backing or flammable less than or to. The current document please contact the Agency flammable solid label denoted by the green color label, in. Obtain the regulations issued under the DOT hazard class system, flammable solids self-reactive substances solid desensitized such. Questions about document content can not be answered by OFR staff special non-smudge label surface and issue certificate. Liquids and similar products, NY 14850. hotel sign vector hotel fire sign search & Navigation shock.